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Academic Journals
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From:Science (Vol. 255, Issue 5048) Peer-ReviewedThe scanning tunneling microscope (STM) can be used to measure current-voltage characteristics on an atomic scale. The attachment of copper phthalocyanine molecules, in contrast to a variety of other molecules, to...
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From:Nature (Vol. 551, Issue 7681) Peer-ReviewedAuthor(s): Peng Wang [1]; Pritha Verma [1]; Guoqin Xia [1]; Jun Shi [2]; Jennifer X. Qiao [3]; Shiwei Tao [2]; Peter T. W. Cheng [2]; Michael A. Poss [3]; Marcus E. Farmer [1]; Kap-Sun Yeung [4]; Jin-Quan Yu...
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From:Canadian Journal of Chemistry (Vol. 85, Issue 9) Peer-ReviewedAbstract: The crystal structures of two molecular clips derived from diethoxycarbonyl glycoluril were reported. Their unique binding behavior towards hydroquinone, which is different from Nolte's clips (high affinity...
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From:Canadian Journal of Chemistry (Vol. 87, Issue 7) Peer-ReviewedWe have computationally explored C-X bond activation by the group-11 transition-metal cations [Cu.sup.+], [Ag.sup.+], and [Au.sup.+], and, for comparison, Pd, using relativistic density functional theory (DFT) at...
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From:Nature (Vol. 464, Issue 7288) Peer-ReviewedOn page 575 of this issue, Sacanna et al. (1) report a simple, scalable method for controlling the orientations of interactions between colloidal particles. Their technique can immediately be applied to existing...
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From:Nature (Vol. 463, Issue 7279) Peer-ReviewedAs a rule of thumb, carbon-carbon bonds are not easily broken. But a tungsten complex has been found to break a particularly strong carbon-carbon bond, opening up fresh opportunities for organic synthesis. Breaking...
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From:Advances in Condensed Matter PhysicsPeer-ReviewedNanomedicine is, generally, the application of nanotechnology to medicine. The term nanomedicine includes monitoring, construction of novel drug delivery systems, and any possible future applications of nanotechnology...
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From:Advanced Materials & Processes (Vol. 175, Issue 7) Peer-ReviewedEngineers at the Massachusetts Institute of Technology (MIT), Cambridge, designed a gel-like material that can be coated onto standard plastic or rubber medical devices such as catheters, providing a surface that not...
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From:Nature (Vol. 505, Issue 7482) Peer-ReviewedSince the nineteenth century, many synthetic organic chemists have focused on developing new strategies to regio-, diastereo- and enantioselectively build carbon-carbon and carbon-heteroatom bonds in a predictable and...
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From:Canadian Journal of Chemistry (Vol. 91, Issue 11) Peer-ReviewedA highly efficient method for the synthesis of [[alpha].sup.1]-oxindole-[alpha]-hydroxyphosphonates via nano-rod ZnO catalyzed hydrophosphonation of isatin derivatives was developed. The reaction products are in...
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From:Canadian Journal of Civil Engineering (Vol. 39, Issue 2) Peer-Reviewed
Bond performance of deformed steel bars in concrete produced with coarse recycled concrete aggregate
Results of an experimental study on the bond performance of deformed steel rebars in concrete made with coarse recycled concrete aggregate (RCA) are presented. The distinctive feature of the study is the new mix... -
From:Science (Vol. 247, Issue 4941) Peer-ReviewedChemical Bond-Making, Bond-Breaking, and Electron Transfer in Solution THE ELECTRONIC THEORY OF ORGANIC CHEMISTRY PROVIDES an extraordinarily powerful intellectual structure for describing the reactivities of the...
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From:Science (Vol. 270, Issue 5236) Peer-ReviewedEvidence exists for an organometallic intermediate, other than vitamin B12, that can make use of the transition-metal alkyl (M-CR3) species. The intermediate consists of a reactive Ni-CH3 fragment, which serves as a...
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From:Canadian Journal of Chemistry (Vol. 93, Issue 10) Peer-ReviewedFull geometry optimization using the BP86 and B3LYP methods has been carried out for all of the low-energy isomers of half-sandwich [L.sub.3]M(Tphn) (Tphn = triphenylene, M = Ti-Ni, and [L.sub.3] = [(CO).sub.3],...
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From:Canadian Journal of Chemistry (Vol. 89, Issue 6) Peer-ReviewedIn this work, we conducted a theoretical study on the addition reactions between ozone and double bonds of terpene molecules such as terpinolene 1, [beta]-phellandrene 2, and limonene 3. Based on the DFT (density...
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From:Polymer Engineering and Science (Vol. 52, Issue 9) Peer-ReviewedThe synthesis of water-dispersilbe graphene nanosheets plays an important role in various practical applications-Herein, we have demonstrated an efficient method for the preparation of water-dispersible graphene hybrid...
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From:Canadian Journal of Chemistry (Vol. 90, Issue 5) Peer-ReviewedDensity functional methods (B3LYP, B3PW91, B3P86, and MPWB95) with [6-31G.sup.**] basis sets and complete basis methods are employed to investigate the bond dissociation energies (BDEs) of the O-N[O.sub.2] bond for...
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From:Polymer Engineering and Science (Vol. 54, Issue 8) Peer-ReviewedThermoreversible crosslinking supramolecular rubber with multiple hydrogen bonds are prepared via reaction of maleic anhydride grafted butyl rubber (MAn-g-IIR) with 3-amino-1,2,4-triazole catalyzed by tetrabutyl...
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From:Canadian Journal of Chemistry (Vol. 95, Issue 11) Peer-ReviewedAbstract: Thiolate-protected gold clusters with precisely controlled atomic composition have recently emerged as promising candidates for a variety of applications because of their unique optical, electronic, and...
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From:Proceedings of the Estonian Academy of Sciences (Vol. 67, Issue 2) Peer-ReviewedThis study demonstrates the promising steps towards improving the detection of small analytes in an aqueous solution by the quartz crystal microbalance (QCM) modified with a molecularly imprinted polymer (MIP) based...