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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedA critical review of zeolites and their use in practical applications is presented. Specificallyconsidered are their role as media for selective light-induced oxidations using molecular [O.sub.2], and the relationship...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedCisplatin is an anticancer drug widely used in the treatment of a wide range of solid tumours (head and neck, lung, bladder etc.), testicular and ovarian cancers. Because of its severe toxicity profile and spontaneous...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedNicotinamide was employed as a supramolecular reagent in the synthesis of six new copper(II) bromo-, iodo-, fluoro- and dibromobenzoate complexes. Structures of [Cu[(2-Brbz).sub.2][(nia).sub.2][([H.sub.2]O).sub.2]] (I),...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedSynthesis and characterization of eight new complexes of various structural types are reported. With 5-nitro-2-furancarboxylic acid (5-N[O.sub.2]-2-fucH), two monomeric complexes, [Cu[(5N[O.sub.2]-2-fuc).sub.2]...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedCobalt(III) complexes with N-salicylidene-2-hydroxy-5-bromobenzylamine ([H.sub.2]sbba) and N-salicylidene-2-hydroxy-5-chlorobenzylamine ([H.sub.2]scba), [n-[([C.sub.4][H.sub.9]).sub.4]N][Co[(sbba).sub.2]] (I) and...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedYttrium and lanthanum amido-complexes with bis(pyrazol-1-yl)acetates in their coordination spheres were studied as the catalysts in [epsilon]-caprolactone and lactide ring-opening polymerisation. A high molecular mass...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedSix copper(II) oxalate complexes, namely [{[K.sub.2][Cu[(ox).sub.2]]}.sub.n] (1), [{[(Hiz).sub.2][Cu[(ox).sub.2]]}.sub.n] (2), [{[Cu(ox) [(N-Bzliz).sub.2]]}.sub.n] (3), [(HMeiz).sub.2][Cu[(ox).sub.2]] (4),...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedInvestigation of salicylatocopper complexes in the presence of a nitrogen donor ligand is a growing research area due to the interesting mimetic activities of such complexes. Here, three X-salicylatocopper (where X =...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedEPR spectroscopy is a well suited analytical tool to monitor the electronic situation around paramagnetic metal centres as copper(II) and therefore the structural influences on the paramagnetic ion....
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From:Chemical Papers (Vol. 70, Issue 1) Peer-Reviewed1,10-Phenanthroline-5,6-dione (Phd) complexes of group 3 and lanthanide elements having formulae Ln[(hfac).sub.3](Phd) (Ln = Y, Eu, Yb; hfac = hexafluoroacetylacetonate) were synthesised and characterised. Complexes of...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedThe XXV. International Conference on Coordination & Bioinorganic Chemistry (XXV. ICCBiC) was held from May 31st to June 5th 2015 in the Smolenice Castle, Slovakia. The conference was organized by the Slovak Chemical...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedA nickel(II) complex, [Ni(taetacn)][(Cl[O.sub.4]).sub.2] x [H.sub.2]O, where taetacn = 1,4,7-tris(2-aminoethyl)-1,4,7- triazacyclononane was synthesized. The crystal structure was determined by the single-crystal X-ray...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedThe influence of [Ca.sup.2+], [Cu.sup.2+] and [Fe.sup.3+]exchanged montmorillonite (MMT) on the type of interaction with aniline in the interlayer space of MMT has been studied by means of X-ray powder diffraction and...
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From:Chemical Papers (Vol. 70, Issue 1) Peer-ReviewedFundamentals of copper catalyzed atom transfer radical addition (ATRA) and mechanistically similar polymerization (ATRP) were discussed. Special emphasis was placed on structural characterization and electrochemical...