Carbene- and carbyne-like behavior of the Mo-P multiple bond in a dimolybdenum complex inducing trigonal-pyramidal coordination of a phosphinidene ligand

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From: Inorganic Chemistry(Vol. 46, Issue 16)
Publisher: American Chemical Society
Document Type: Article
Length: 44 words

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Abstract :

The phosphinidene complex is shown to have different Mo-P bonds and has displayed a high reactivity located at the short Mo-P bond. The analysis has shown that the P atoms have displayed an unprecedented trigonal-pyramidal-like environment, instead of the expected tetrahedral distribution of bonds.

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Gale Document Number: GALE|A168076088