Allylation and Heterocycloaddition Reactions of Aldimines: Furan- and Quinolinecarboxaldehydes/Allylierungs- und Heterocycloadditionsreaktionen von Aldiminen: Furan- undChinolincarboxaldehyde

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From: Monatshefte für Chemie / Chemical Monthly(Vol. 129, Issue 6-7)
Publisher: Springer
Document Type: Report
Length: 219 words

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To access, purchase, authenticate, or subscribe to the full-text of this article, please visit this link: http://dx.doi.org/10.1007/PL00013465 Byline: Vladimir Kouznetsov (2), Nuket Ocal (1), Zuhal Turgut (1), Fedor Zubkov (3), Seniz Kaban (1), Alexei V. Varlamov (3) Keywords: Keywords.aDiels-Alder adduct [alpha]-Furfurylidenbenzilamine Nitrone [alpha]-Substituted furan 4-Thiazolidinone. Abstract: aNew derivatives of [alpha]-substituted furans were prepared in high yields from easily available [alpha]-furfurylidenbenzilamines via nucleophilic C-allylation. The homoallylamines obtained this way were used for the synthesis of some polyfunctional aminobutene derivatives. In addition, 4-thiazolidinones some of which are hetaryl substituted at the 2-position were prepared by the reaction of mercapto acids with quinoline carboxaldehydes and p-phenetidine. All new products were fully characterized. Abstract (German): aAus den leicht zuganglichen [alpha]-Furfurylidenbenzilaminen wurden durch nucleophile C-Allylierung neue Derivative [alpha]-substituierter Furane mit hohen Ausbeuten dargestellt. Die dabei gewonnenen Homoallylamine wurden fur die Synthese von polyfunktionalen Aminobutenderivaten eingesetzt. Daruber hinaus wurden durch Reaktion von Merkaptosauren mit Chinolincarboxaldehyden und p-Phenetidin an der 2-Stelle heterosubstituierte 4-Thiazolidinone gebildet. Alle Produkte wurden entsprechend charakterisiert. Author Affiliation: (1) aYA[+ or -]ldA[+ or -]z Technical University, Department of Chemistry, 80270 SiAli, A[degrees]stanbul, Turkey, TR (2) aSchool of Chemistry, Industrial University of Santander, Bucaramanga, Colombia, CO (3) aDepartment of Organic Chemistry, Russian Peoples Friendshi, RU Article History: Registration Date: 05/01/1998 Online Date: 06/01/1998 Article note: Received January 12, 1998. Accepted (revised) February 28, 1998

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Gale Document Number: GALE|A464250436