Indium-mediated asymmetric barbier-type allylation of aldimines in alcoholic solvents: Synthesis of optically active homoallylic amines

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From: Journal of Organic Chemistry(Vol. 70, Issue 9)
Publisher: American Chemical Society
Document Type: Article
Length: 33 words

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Abstract :

A highly distereoselective allylation of chiral aldimides derived from optically active phenylglycinol mediated by indium metal in alcoholic solvents is demonstrated. Further, a racemization-free protocol for removal of the chiral auxiliary is developed.

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Gale Document Number: GALE|A133124375