Synthesis, electrochemical, and photophysical study of covalently linked porphyrin dimers with two different macrocycles

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From: Inorganic Chemistry(Vol. 37, Issue 10)
Publisher: American Chemical Society
Document Type: Article
Length: 54 words

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Abstract :

Four unsymmetrical covalently linked porphyrin dimers were synthesized and their electrochemical, spectroelectrochemical and/or photophysical characteristics were investigated. Computed energy transfer rate constants were observed to be consistent with the empirical data and indicated that the energy transfer mechanisms are best represented by a Foster process. Highly efficient and directional energy transfer processes were observed.

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Gale Document Number: GALE|A20810497