Mechanisms of peroxynitrous acid and methyl peroxynitrite, ROONO (R = H, Me). rearragnements: conformation-dependent homolytic dissociation

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Date: July 8, 2004
From: Journal of Physical Chemistry A(Vol. 108, Issue 27)
Publisher: American Chemical Society
Document Type: Article
Length: 32 words

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Abstract :

The O-O bond breaking reactions of methyl peroxynitrite and peroxynitrous acid was investigated using various methods. Analyses have confirmed that RO/NO2radical pairs are readily formed from cis-ROONO conformations than from trans-ROONO conformations.

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Gale Document Number: GALE|A122847062